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Organic Chemistry 51C. Lecture 19. Organometallic Reactions in Organic Synthesis.

Journal of Physical Chemistry B. Optical anisotropy of porphyrin Langmuir-Blodgett films. Surface Science. Porphyrinic molecular devices: towards nanoscaled processes. International Journal of Molecular Sciences. Molecular organization and syn reversible arrow anti conformational equilibria in ethane-bridged bis zinc porphyrin floating films at the air-water interface.

Imahori H and Umeyama T. Porphyrin-modified electrodes for solar energy conversion. Hasobe T. Porphyrin-based supramolecular nanoarchitectures for solar energy conversion. Journal of Physical Chemistry Letters. Synthesis, electrochemistry, Langmuir-Blodgett deposition and photophysics of metal-coordinated fullerene-porphyrin dyads.

Journal of Organometallic Chemistry. Highly asymmetrical porphyrins with enhanced push-pull character for dye-sensitized solar cells. Chemistry A European Journal. Angewandte Chemie International Edition. Pairing fullerenes and porphyrins: supramolecular wires that exhibit charge transfer activity. Journal of the American Chemical Society.

Supramolecular Organic and Organometallic Chemistry Centre

Synthesis and characterization of porphyrin-terthiophene and oligothiophene pi-conjugated copolymers for polymer solar cells. European Polymer Journal. Iron III porphyrin anchored onto organosilylated multiwalled carbon nanotubes as an active catalyst for epoxidation reactions under mild conditions. Journal of Materials Science. New manganese porphyrin as biomimetic catalyst of cyclohexane oxidation: effect of water or imidazole as additives.

Applied Catalysis A: General. Optical properties and sensor applications of bimetallic nanostructures of porphyrins. New composite porphyrin-conductive polymer gas sensors for application in electronic noses. Handbook of Porphyrin Science. Washington: World Scientific Publishing Company; Kinetic behavior analysis of porphyrin Langmuir-Blodgett films for conductive gas sensors. Journal of Applied Physics. Development and optimization of porphyrin gas sensing LB films.

Recommended pages

Advances in Colloid and Interface Science. Gas-sensing properties of porphyrin dimer Langmuir-Blodgett films. Thin Solid Films. Hirano C and Imae T. Electrochemical properties of protoporphyrin IX zinc II films. Journal of Colloid and Interface Science. Conformational preference of a porphyrin rotor in confined environments. RSC Advances.

ACS Nano. Li C and Imae T.


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Giancane G and Valli L. State of art in porphyrin Langmuir-Blodgett films as chemical sensors. Preparation of hybrid films containing gold nanoparticles and cobalt porphyrin with flexible electrochemical properties. Layer-by-layer assembly of Zn II and Ni II 5,10,15,tetra 4-ethynylphenyl porphyrin multilayers on Au using copper catalyzed azide-alkyne cycloaddition. Syn-anti conformation switching of a bis-porphyrin derivative at the air-water interface and in the solid state as an effective tool for chemical sensing.

Soft Matter. Gupta I and Ravikanth M.

Organic–inorganic supramolecular solid catalyst boosts organic reactions in water

Recent developments in heteroporphyrins and their analogues. Coordination Chemistry Reviews. On preparation of metalloporphyrins. With almost 30 years of history, the UJI ranks among the best universities in the world, according to the World University Rankings , conducted by The Times Higher Education, that places it in 12th place out of the 38 participating Spanish universities and the second in the Valencian Community.

Functional structures in nature often assemble with high geometric precision from libraries of different building blocks. The rational design of programmed artificial supramolecular architectures depends on how to control the sequence and position of the building blocks in the final assemblies. The application of the general principles and stereoelectronic preferences of metal ions combined with rigid multidentate ligands has allowed the rational design of a wide range of highly symmetric architectures.

Supramolecular coordination complexes SCCs are often referred to as "molecular flasks" because they show well-defined nanoscopic cavities. Over the last few years, we designed a wide variety of mono- di- and tri-NHC-based ligands bearing rigid polycyclic aromatic functionalities, thus we now have access to a wide library of scaffolds that can be used for the preparation of a large number of organometallic-based supramolecular structures.

These structures have the potential to be utilized in homogeneous catalysis and host-guest chemistry. Considering these precedents, this new proposal attempts to design organometallic Supramolecular Coordination Complexes SSCs for the selective recognition of organic substrates and for the preparation of new homogeneous supramolecular catalysts. For this latter point, we will focus our interest in exploiting the supramolecular interactions established between the catalyst host and the substrate guest to induce enhanced activities and selectivities.

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Skip to Main Content. Supramolecular Organometallic Chemistry Author s : Prof. Ionel Haiduc Prof. Frank T. First published: 12 October About this book Supramolecular chemistry has become not only a major field of chemistry, but is also a vivid interface between chemistry, biology, physics, and materials science. Although still a relatively young field, termini such as molecular recognition, host-guest chemistry, or self-assembly are now common knowledge even for chemistry students, and research has already been honored with a Nobel Prize.